3886-70-2
- Product Name:(R)-(+)-1-(1-Naphthyl)ethylamine
- Molecular Formula:C12H13N
- Purity:99%
- Molecular Weight:171.242
Product Details
Quality Factory Supply Hot Sale (R)-(+)-1-(1-Naphthyl)ethylamine 3886-70-2 with Safe Transportation
- Molecular Formula:C12H13N
- Molecular Weight:171.242
- Appearance/Colour:Colorless to light yellow liquid
- Vapor Pressure:0.00214mmHg at 25°C
- Melting Point:135-136 °C
- Refractive Index:n20/D 1.623(lit.)
- Boiling Point:289.9 °C at 760 mmHg
- PKA:9.26±0.40(Predicted)
- Flash Point:144.3 °C
- PSA:26.02000
- Density:1.064 g/cm3
- LogP:3.55980
(R)-(+)-1-(1-Naphthyl)ethylamine(Cas 3886-70-2) Usage
Chemical Properties |
Colorless to light yellow liqui |
Uses |
(R)-(+)-1-(1-Naphthyl)ethylamine is used in chiral synthesis in organic reactions including the synthesis of β-amino acids and the enantioselective of ketones to nitroolefins. |
General Description |
(R)-(+)-1-(1-Naphthyl)ethylamine is a chiral derivatization reagent useful for all gas chromatography (GC) applications in the chiral field. It is specially selected to meet the requirements for derivatization reagents for enantiomeric excess determinations. |
InChI:InChI=1/C12H13N/c1-9(13)11-8-4-6-10-5-2-3-7-12(10)11/h2-9H,13H2,1H3/p+1/t9-/m1/s1
3886-70-2 Relevant articles
A METHOD FOR PREPARATION OF DIASTEREOMERIC LACTATE SALTS OF 1-(1-NAPHTHYL)ETHYL AMINE AND PURE ENANTIOMERS OF 1-(1-NAPHTHYL)ETHYL AMINE
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Paragraph 0048, (2021/09/11)
The invention relates to method for prep...
Asymmetric reduction method of nitrogen-phosphonyl protected imine
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Paragraph 0180-0185, (2021/01/15)
The invention discloses an asymmetric re...
Enzymatic Primary Amination of Benzylic and Allylic C(sp3)-H Bonds
Jia, Zhi-Jun,Gao, Shilong,Arnold, Frances H.
supporting information, p. 10279 - 10283 (2020/07/27)
Aliphatic primary amines are prevalent i...
Addition of Highly Polarized Organometallic Compounds to N-tert-Butanesulfinyl Imines in Deep Eutectic Solvents under Air: Preparation of Chiral Amines of Pharmaceutical Interest
Capriati, Vito,Cicco, Luciana,García-álvarez, Joaquín,González-Sabín, Javier,Perna, Filippo M.,Ríos-Lombardía, Nicolás,Salomone, Antonio,Vitale, Paola
, (2020/07/04)
Highly polarized organometallic compound...
3886-70-2 Process route
- 10420-89-0
(S)-1-(1-Naphthyl)ethylamine
- 100-41-4,27536-89-6
ethylbenzene
- 3886-70-2
(R)-1-(1-Naphthyl)ethylamine
Conditions | Yield |
---|---|
With hydrogen; Pd-BaSO4; In toluene; at 70 ℃; for 24h; under 75.0075 Torr;
|
- 42882-31-5
(RS)-1-(1-naphthyl)ethylamine
- 3886-70-2
(R)-1-(1-Naphthyl)ethylamine
Conditions | Yield |
---|---|
With p-chlorophenyl pentanoate; hydrogen; In toluene; at 55 ℃; for 15h; under 75.0075 Torr; Enzymatic reaction;
|
88.3% |
With D-(+)-camphoric acid;
|
|
Multi-step reaction with 3 steps
1: ethanol / 0.75 h / 60 - 65 °C / Resolution of racemate
2: ammonia / water; toluene
3: potassium hydroxide / dimethyl sulfoxide / 20 h / 150 - 160 °C
With ammonia; potassium hydroxide; In ethanol; water; dimethyl sulfoxide; toluene;
|
|
Multi-step reaction with 2 steps
1: water; methanol / 10 h / 60 - 65 °C
2: sodium hydroxide / water; toluene / 0.5 h / 25 - 35 °C / pH 12.5 - 13.5
With sodium hydroxide; In methanol; water; toluene;
|
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